Impact dynamics of colloidal quantum dot solids.

نویسندگان

  • Lejun Qi
  • Peter H McMurry
  • David J Norris
  • Steven L Girshick
چکیده

We use aerosol techniques to investigate the cohesive and granular properties of solids composed of colloidal semiconductor nanocrystals (quantum dot solids). We form spherical agglomerates of nanocrystals with a nebulizer and direct them toward a carbon substrate at low (~0.01 m/s) or high (~100 m/s) velocities. We then study the morphology of the deposit (i.e., the "splat") after impact. By varying the size of the agglomerate and the spacing between the nanocrystals within it, we observe influences on the mechanical properties of the quantum dot solid. We observe a liquid-to-solid transition as the nanocrystals become more densely packed. Agglomerates with weakly interacting nanocrystals exhibit liquidlike splashing and coalescence of overlapping splats. More dense agglomerates exhibit arching and thickening effects, which is behavior typical of granular materials.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Effect of PbS Film Thickness on the Performance of Colloidal Quantum Dot Solar Cells

Colloidal quantum dots offer broad tuning of semiconductor band structure via the quantum size effect. In this paper, we present a detailed investigation on the influence of the thickness of colloidal lead sulfide (PbS) nanocrystals (active layer) to the photovoltaic performance of colloidal quantum dot solar cells. The PbS nanocrystals (QDs) were synthesized in a non-coordinating solvent, 1-oc...

متن کامل

Introducing nanostructure patterns for performance enhancement in PbS colloidal quantum dot solar cells

With attention to the thin film structure of colloidal quantum dot solar cells, in this paper in order to improvement of active layer absorption of them, we have proposed the use of nanostructure pattern for enhancement of their performance. For this purpose we have presented suitable nano hemisphare patterns in colloidal quantum dot solar cells for light trapping in absorption layer. Then with...

متن کامل

Quantum junction solar cells.

Colloidal quantum dot solids combine convenient solution-processing with quantum size effect tuning, offering avenues to high-efficiency multijunction cells based on a single materials synthesis and processing platform. The highest-performing colloidal quantum dot rectifying devices reported to date have relied on a junction between a quantum-tuned absorber and a bulk material (e.g., TiO(2)); h...

متن کامل

Microsecond-sustained lasing from colloidal quantum dot solids

Colloidal quantum dots have grown in interest as materials for light amplification and lasing in view of their bright photoluminescence, convenient solution processing and size-controlled spectral tunability. To date, lasing in colloidal quantum dot solids has been limited to the nanosecond temporal regime, curtailing their application in systems that require more sustained emission. Here we fi...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Langmuir : the ACS journal of surfaces and colloids

دوره 27 20  شماره 

صفحات  -

تاریخ انتشار 2011